近期，我院教师魏涛等的研究成果“An intermittent lithium deposition model based on bimetallic MOFs derivatives for dendrite-free lithium anode with ultrahigh areal capacity”在《Chinese Chemical Letters》（IF=9.1）上发表。

近期，我院教师魏涛等的研究成果“An intermittent lithium deposition model based on bimetallic MOFs derivatives for dendrite-free lithium anode with ultrahigh areal capacity”在《Chinese Chemical Letters》（IF=9.1）上发表。

论文简介如下：

In the development of 3D conductive frameworks for lithium metal anode (LMA), two models have been proposed: top growth model and bottom-up growth model. However, Li tends to accumulate on the top of these 3D frameworks with homogenous lithiophilicity (top growth) and Li dendrite still forms. To address this issue, some researchers have focused on developing 3D frameworks with gradient lithiophilicity, which realized bottom-up growth of Li. Nevertheless, partial Li nucleation sites on the top of these frameworks were missed. Inspired by the two models talked above, this work firstly proposed a novel intermittent lithiophilic model for lithium deposition. To demonstrate the feasibility of this model, a bimetallic metal-organic frameworks derived ZnMn₂O₄-MnO nanoparticles were grown on carbon cloth for LMA. It can cycle stably under ultra-high current and areal capacity (10 mA/cm², 10 mAh/cm²). The in-situ optical microscopy (OM) was conducted to observe the Li deposition behavior, no dendrite was found during 80 h in ester-based electrolyte while the pure Li only cycled for 2 h. What is more, it can also be well-coupled with LiNi_0.8Co_0.1Mn_0.1O₂ (NCM811) cathode and solid-state electrolyte, which further prove the advantages of the intermittent model for the development of LMAs with high safety and high energy density.

全文下载：https://doi.org/10.1016/j.cclet.2023.109122